Prime For Scientific and Technical Supplies - Comparison Between Different Methods of Moisture Analysis

By Ziryab Imad Ali Ahmed June 4, 2018 Application Knowledge 1 comment

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The moisture of a sample is not only the water content in the material. “Material moisture” is understood to be all volatile substances which escape during heating and result in a weight loss of a sample. These include:

 Water • Fats • Oils • Alcohols • Organic solvents • Flavorings • Volatile constituents • Where necessary, Decomposing substance (if heated too strongly)

A variety of methods exist to determine the moisture content of a sample. The methods can be divided in two categories:

The absolute method is used to directly determine the moisture content of a sample (e.g. weight loss by drying). These methods include drying in the drying cabinet, infrared drying and micro-wave drying. All three methods work thermogravimetrically.

Indirect determination is carried out by means of the derived methods. A physical property is measured which is in connection with the moisture (e.g. absorption of electromagnetic radiation). These methods include the Karl-Fischer titration, the infrared spectroscopy, the micro-wave spectroscopy, etc.

Drying methods:
Halogen moisture analyzer 
Drying cabinet method 
Micro-wave dryer Karl-Fischer method

Why do different methods determine different material moistures?

The drying cabinet evaporates – beside water – also slightly volatile constituents. Often the sample is not dried completely due to the weak heating by means of convection heat. The measuring value is above the water content but below the total moisture content.

The infrared or halogen dryer evaporates – beside water – also highly or hardly volatile constituents. The total moisture of the sample is determined by intensive heating using the absorption drying method. In most cases, the measuring value is above the reference method of the drying cabinet. (Problems: e.g. pore sealing, surface burns)

A micro-wave dryer evaporates - beside water – only low amounts of highly volatile constituents. Due to absorption drying – orientated to dipoles – the measuring value is very close at the water content and thus below the value of the drying cabinet.

The Karl-Fischer titration method determines the number of water molecules by a chemical reaction. The measuring value corresponds to the water content with highest accuracy.

Two reference methods are recognized internationally: 

• The drying cabinet method to determine the material moisture 
• The Karl-Fischer titration to determine the water content • All other methods have to be adapted to one of the two methods, if necessary!

Drying cabinet method 

For the traditional drying cabinet method, a hot air flow heats the sample from outside to inside against the flow of the rising moisture and the evaporation coldness at the surface. Often long drying periods are required. A drying cabinet is an apparatus to de-moisture an item mostly by de-moistening the air and using hygroscopic materials (sorbents). Drying  cabinets are offered for temperature ranges from room temperature up to approx. 250 °C.

For more information on ovens click here


Karl-Fischer method 



                                                         





















                                                          
                                                         

This method is used to determine the amount of water content. Here, the specific reaction of water to a Karl Fischer reagent is used which contains iodine, sulphur dioxide and pyridine in the presence of methanol. This method can be applied either as coulometric titration or volumetric titration. For the coulometric titration, the sample is added to the Karl Fischer reagent and subjected to electrolytic oxidation in order to produce iodine. As the iodine is generated according to Faraday’s law related to the amount of electricity, the amount of water can be determined immediately according to the amount of electricity which is required for electrolytic oxidation. For the volumetric titration, the sample is added to an appropriate dehydrated solvent in a titration flask which had been dehydrated by means of a titrant. Titration is then carried out by means of a titrant with previously standardized titer (mg H2O/ml). The moisture content of the sample is determined from the titration volume (ml). Automatic volumetric titrators on the basis of these methods are commercially available.

For more information on automatic titrators click here

Thermo-gravimetric measurement by means of halogen moisture analyzer 



The KERN halogen moisture analyzer supplies quick and reliable measuring results. The instruments measure according to the principle of thermo-gravimetry. The sample is weighed and heated by a halogen lamp (infrared radiation). The weight loss is recorded continuously and drying is finished according to a defined criterion. The moisture content is calculated automatically from the weight difference. Drying by means of halogen spotlights is a further development of the infrared drying method. During the drying process in a halogen moisture analyzer, the sample absorbs the infrared radiation of a halogen lamp. Radiation penetrates most part of the sample and is converted there in heat energy. In this way, the sample is heated very quickly. A low part of the radiation is reflected by the sample or passes the latter. The amount of reflected radiation depends to a large part on the fact whether it is a light or a dark sample.
 You know this effect from everyday life: If you wear dark clothes and stay in the sun you feel much warmer than when wearing a white shirt. In any case, a slightly lower drying temperature should be selected for a darker substance than for a lighter sample. The depth of penetration of the IR radiation depends on the permeability of the sample. At a lower permeability, the IR radiation penetrates only the top layers. Thus the heat conductivity of the substance is decisive for the further transport of heat into the deeper layers. The higher the heat conductivity the more quickly and homogenously the sample is heated.

For more information on automatic titrators click here 


In the upcoming application notes, we will discuss the various applications of the moisture analyzer and how to carry out different measurements with it.



References:

2. http://dok.kern-sohn.com/manuals/files/English/Application%20Note_Moisture%20analyzer-ZB-e-1210.pdf

Ziryab Imad Ali Ahmed

Ziryab Imad, is the Commercial Manager for Prime for Scientific and Technical Supplies and specializes in: density measurement, viscosity measurement, optical measurement techniques, sample preparation, and petroleum testing instruments. He has extensive experience in providing effective solutions to clients in different industries using the Anton Paar portfolio, unique for its innovative measuring solutions. He is passionate about doing things in an unorthodox manner to achieve greatest success.

1 comment
Pitt December 5, 2018

Thanks for your sharing. Moisture analyzer combines state-of-the-art heating with highly accurate weighing technology to deliver a faster, more precise method of moisture analysis. For more information, welcome to click on https://www.testextextile.com/product/moisture-analyzer-tf123a/

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